| Spotlights |
| Spotlights on Recent JACS Publications |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14265-14266 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Catalytic Activity of Macroion–Porphyrin Nanoassemblies |
| Sabine Frühbeißer and Franziska Gröhn |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14267-14270 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| ultiple Functionalities of Polyfluorene Grafted with Metal Ion-Intercalated Crown Ether as an Electron Transport Layer for Bulk-Heterojunction Polymer Solar Cells: Optical Interference, Hole Blocking, |
| Sih-Hao Liao, Yi-Lun Li, Tzu-Hao Jen, Yu-Shan Cheng, and Show-An Chen |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14271-14274 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Water Oxidation Catalyzed by Cobalt(II) Adsorbed on Silica Nanoparticles |
| Tomer Zidki, Lihua Zhang, Vladimir Shafirovich, and Sergei V. Lymar |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14275-14278 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Quantum Switching of π-Electron Rotations in a Nonplanar Chiral Molecule by Using Linearly Polarized UV Laser Pulses |
| Hirobumi Mineo, Masahiro Yamaki, Yoshiaki Teranishi, Michitoshi Hayashi, Sheng Hsien Lin, and Yuichi Fujimura |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14279-14282 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Synthesis of Ultralong Copper Nanowires for High-Performance Transparent Electrodes |
| Dieqing Zhang, Ranran Wang, Meicheng Wen, Ding Weng, Xia Cui, Jing Sun, Hexing Li, and Yunfeng Lu |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14283-14286 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Water-Soluble Narrow-Line Radicals for Dynamic Nuclear Polarization |
| Olesya Haze, Björn Corzilius, Albert A. Smith, Robert G. Griffin, and Timothy M. Swager |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14287-14290 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| One-Pot in Situ Fabrication of Stable Nanocaterpillars Directly from Polyacetylene Diblock Copolymers Synthesized by Mild Ring-Opening Metathesis Polymerization |
| Ki-Young Yoon, In-Hwan Lee, Kyung Oh Kim, Jihoon Jang, Eunji Lee, and Tae-Lim Choi |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14291-14294 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| A New Binding Motif of Sterically Demanding Thiolates on a Gold Cluster |
| Jun-ichi Nishigaki, Risako Tsunoyama, Hironori Tsunoyama, Nobuyuki Ichikuni, Seiji Yamazoe, Yuichi Negishi, Mikinao Ito, Tsukasa Matsuo, Kohei Tamao, and Tatsuya Tsukuda |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14295-14297 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Metavanadate at the Active Site of the Phosphatase VHZ |
| Vyacheslav I. Kuznetsov, Anastassia N. Alexandrova, and Alvan C. Hengge |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14298-14301 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| The Crystalline Structure of Copper Phthalocyanine Films on ZnO(11̅00) |
| Amy C. Cruickshank, Christian J. Dotzler, Salahud Din, Sandrine Heutz, Michael F. Toney, and Mary P. Ryan |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14302-14305 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Do Deuteriums Form Stronger CH−π Interactions? |
| Chen Zhao, Robert M. Parrish, Mark D. Smith, Perry J. Pellechia, C. David Sherrill, and Ken D. Shimizu |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14306-14309 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Development of a Fluorogenic Probe with a Transesterification Switch for Detection of Histone Deacetylase Activity |
| Reisuke Baba, Yuichiro Hori, Shin Mizukami, and Kazuya Kikuchi |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14310-14313 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Catalytic Boracarboxylation of Alkynes with Diborane and Carbon Dioxide by an N-Heterocyclic Carbene Copper Catalyst |
| Liang Zhang, Jianhua Cheng, Béatrice Carry, and Zhaomin Hou |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14314-14317 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Toward Quantifying the Electrostatic Transduction Mechanism in Carbon Nanotube Molecular Sensors |
| Mitchell B. Lerner, James M. Resczenski, Akshay Amin, Robert R. Johnson, Jonas I. Goldsmith, and A. T. Charlie Johnson |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14318-14321 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Axially Chiral Triazoloisoquinolin-3-ylidene Ligands in Gold(I)-Catalyzed Asymmetric Intermolecular (4 + 2) Cycloadditions of Allenamides and Dienes |
| Javier Francos, Francisca Grande-Carmona, Hélio Faustino, Javier Iglesias-Sigüenza, Elena Díez, Isaac Alonso, Rosario Fernández, José M. Lassaletta, Fernando López, and José L. Mascareñas |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14322-14325 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Copper-Catalyzed Desymmetric Intramolecular Ullmann C–N Coupling: An Enantioselective Preparation of Indolines |
| Fengtao Zhou, Jiajia Guo, Jianguang Liu, Ke Ding, Shouyun Yu, and Qian Cai |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14326-14329 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Silver-Catalyzed Decarboxylative Alkynylation of Aliphatic Carboxylic Acids in Aqueous Solution |
| Xuesong Liu, Zhentao Wang, Xiaomin Cheng, and Chaozhong Li |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14330-14333 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Asymmetric Synthesis of Trifluoromethylated Amines via Catalytic Enantioselective Isomerization of Imines |
| Yongwei Wu and Li Deng |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14334-14337 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| CO2 Dynamics in a Metal–Organic Framework with Open Metal Sites |
| Xueqian Kong, Eric Scott, Wen Ding, Jarad A. Mason, Jeffrey R. Long, and Jeffrey A. Reimer |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14341-14344 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Ruthenium Catalyzed Hydroboration of Terminal Alkynes to Z-Vinylboronates |
| Chidambaram Gunanathan, Markus Hölscher, Fangfang Pan, and Walter Leitner |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14349-14352 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Understanding the Metal-Directed Growth of Single-Crystal M-TCNQF4 Organic Nanowires with Time-Resolved, in Situ X-ray Diffraction and First-Principles Theoretical Studies |
| Kai Xiao, Mina Yoon, Adam J. Rondinone, Edward A. Payzant, and David B. Geohegan |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14353-14361 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| First Principles Simulations of the Electrochemical Lithiation and Delithiation of Faceted Crystalline Silicon |
| Maria K. Y. Chan, C. Wolverton, and Jeffrey P. Greeley |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14362-14374 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Shedding Light on Helical Microtubules: Real-Time Observations of Microtubule Self-Assembly by Light Microscopy |
| Hee-Young Lee, Hyuntaek Oh, Jae-Ho Lee, and Srinivasa R. Raghavan |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14375-14381 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| The Role of Organic Linkers in Directing DNA Self-Assembly and Significantly Stabilizing DNA Duplexes |
| Andrea A. Greschner, Violeta Toader, and Hanadi F. Sleiman |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14382-14389 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Multistate Organization of Transmembrane Helical Protein Dimers Governed by the Host Membrane |
| Anton A. Polyansky, Pavel E. Volynsky, and Roman G. Efremov |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14390-14400 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Simulation of Metal–Ligand Self-Assembly into Spherical Complex M6L8 |
| Makoto Yoneya, Tomohiko Yamaguchi, Sota Sato, and Makoto Fujita |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14401-14407 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Sulfur K-edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory of Dithiophosphinate Extractants: Minor Actinide Selectivity and Electronic Structure Correlations |
| Scott R. Daly, Jason M. Keith, Enrique R. Batista, Kevin S. Boland, David L. Clark, Stosh A. Kozimor, and Richard L. Martin |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14408-14422 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Multiferroic Materials Based on Organic Transition-Metal Molecular Nanowires |
| Menghao Wu, J. D. Burton, Evgeny Y. Tsymbal, Xiao Cheng Zeng, and Puru Jena |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14423-14429 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| γ-Alumina: The Essential and Unexpected Role of Water for the Structure, Stability, and Reactivity of “Defect” Sites |
| Raphael Wischert, Pierre Laurent, Christophe Copéret, Françoise Delbecq, and Philippe Sautet |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14430-14449 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Observation of Negative and Positive Trions in the Electrochemically Carrier-Doped Single-Walled Carbon Nanotubes |
| Jin Sung Park, Yasuhiko Hirana, Shinichiro Mouri, Yuhei Miyauchi, Naotoshi Nakashima, and Kazunari Matsuda |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14461-14466 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Fluorescence Quenching Studies of Potential-Dependent DNA Reorientation Dynamics at Glassy Carbon Electrode Surfaces |
| Qin Li, Chenchen Cui, Daniel A. Higgins, and Jun Li |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14467-14475 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Raising the Speed Limit for β-Hairpin Formation |
| Caitlin M. Davis, Shifeng Xiao, Daniel P. Raleigh, and R. Brian Dyer |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14476-14482 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Probing Cation and Vacancy Ordering in the Dry and Hydrated Yttrium-Substituted BaSnO3 Perovskite by NMR Spectroscopy and First Principles Calculations: Implications for Proton Mobility |
| Lucienne Buannic, Frédéric Blanc, Derek S. Middlemiss, and Clare P. Grey |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14483-14498 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Unmediated by DNA Electron Transfer in Redox-Labeled DNA Duplexes End-Tethered to Gold Electrodes |
| Alireza Abi and Elena E. Ferapontova |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14499-14507 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Evidence of Nonelectrochemical Shift Reaction on a CO-Tolerant High-Entropy State Pt–Ru Anode Catalyst for Reliable and Efficient Residential Fuel Cell Systems |
| Tatsuya Takeguchi, Toshiro Yamanaka, Kiyotaka Asakura, Ernee Noryana Muhamad, Kohei Uosaki, and Wataru Ueda |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14508-14512 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Stable Tetrabenzo-Chichibabin’s Hydrocarbons: Tunable Ground State and Unusual Transition between Their Closed-Shell and Open-Shell Resonance Forms |
| Zebing Zeng, Young Mo Sung, Nina Bao, Davin Tan, Richmond Lee, José L. Zafra, Byung Sun Lee, Masatoshi Ishida, Jun Ding, Juan T. López Navarrete, Yuan Li, Wangdong Zeng, Dongho Kim, Kuo-Wei Huang, Richard D. Webster, Juan Casado, and Jishan Wu |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14513-14525 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Preparation of Au/CeO2 Exhibiting Strong Surface Plasmon Resonance Effective for Selective or Chemoselective Oxidation of Alcohols to Aldehydes or Ketones in Aqueous Suspensions under Irradiation by Green Light |
| Atsuhiro Tanaka, Keiji Hashimoto, and Hiroshi Kominami |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14526-14533 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Nanostructured Block-Random Copolymers with Tunable Magnetic Properties |
| Yongping Zha, Hitesh D. Thaker, Raghavendra R. Maddikeri, Samuel P. Gido, Mark T. Tuominen, and Gregory N. Tew |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14534-14541 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Defining Rules for the Shape Evolution of Gold Nanoparticles |
| Mark R. Langille, Michelle L. Personick, Jian Zhang, and Chad A. Mirkin |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14542-14554 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| p53 Searches on DNA by Rotation-Uncoupled Sliding at C-Terminal Tails and Restricted Hopping of Core Domains |
| Tsuyoshi Terakawa, Hiroo Kenzaki, and Shoji Takada |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14555-14562 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Pd(II)-Catalyzed Regioselective 2-Alkylation of Indoles via a Norbornene-Mediated C–H Activation: Mechanism and Applications |
| Lei Jiao, Eberhardt Herdtweck, and Thorsten Bach |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14563-14572 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Role of Nanomechanics in Canonical and Noncanonical Pro-angiogenic Ligand/VEGF Receptor-2 Activation |
| Daniele Maiolo, Stefania Mitola, Daria Leali, Giulio Oliviero, Cosetta Ravelli, Antonella Bugatti, Laura E. Depero, Marco Presta, and Paolo Bergese |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14573-14579 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Proton Transfer from C-6 of Uridine 5′-Monophosphate Catalyzed by Orotidine 5′-Monophosphate Decarboxylase: Formation and Stability of a Vinyl Carbanion Intermediate and the Effect of a 5-Fluoro Substituent |
| Wing-Yin Tsang, B. McKay Wood, Freeman M. Wong, Weiming Wu, John A. Gerlt, Tina L. Amyes, and John P. Richard |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14580-14594 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| The Role of Group 14 Element Hydrides in the Activation of C–H Bonds in Cyclic Olefins |
| Owen T. Summerscales, Christine A. Caputo, Caroline E. Knapp, James C. Fettinger, and Philip P. Power |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14595-14603 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Polysulfide Chalcogels with Ion-Exchange Properties and Highly Efficient Mercury Vapor Sorption |
| Youngtak Oh, Collin D. Morris, and Mercouri G. Kanatzidis |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14604-14608 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Variable-Temperature 17O NMR Studies Allow Quantitative Evaluation of Molecular Dynamics in Organic Solids |
| Xianqi Kong, Luke A. O’Dell, Victor Terskikh, Eric Ye, Ruiyao Wang, and Gang Wu |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14609-14617 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Mass Action at the Single-Molecule Level |
| Min Ju Shon and Adam E. Cohen |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14618-14623 |
| http://pubs.acs.org/toc/jacsat/134/35 |
| Search for a Small Chromophore with Efficient Singlet Fission: Biradicaloid Heterocycles |
| Akin Akdag, Zdeněk Havlas, and Josef Michl |
| JL OF THE AM CHEMICAL SOCIETY |
| 2012 |
| vol.134 no.35 pp.14624-14631 |
| http://pubs.acs.org/toc/jacsat/134/35 |