Inorganic chemistry v.50 n.7 2011

ISSN 0020-1669

A Novel 9-MC-3 and 15-MC-6 Onset Stacked Metallacrown Single-Molecule Magnet: Synthesis and Crystal Structure

Suna Wang, Lingqian Kong, Hua Yang, Zhoutong He, Zheng Jiang, Dacheng Li, Suyuan Zeng, Meiju Niu, You Song, and Jianmin Dou

pp 2705–2707

Publication Date (Web): March 3, 2011 (Communication)

DOI: 10.1021/ic101622d

Intervalence Charge-Transfer System by 1D Assembly of New Mixed-Valence Octanuclear Cu^I/Cu^II/Cu^III Cluster Units

Takashi Okubo, Hiroyasu Kuwamoto, Kyung Ho Kim, Shinya Hayami, Akihito Yamano, Motoo Shiro, Masahiko Maekawa, and Takayoshi Kuroda-Sowa

pp 2708–2710

Publication Date (Web): February 28, 2011 (Communication)

DOI: 10.1021/ic101794u

A Selective Colorimetric Hg²⁺ Probe Featuring a Styryl Dithiaazacrown Containing Platinum(II) Terpyridine Complex through Modulation of the Relative Strength of ICT and MLCT Transitions

Sung-Kuang Chung, Yong-Ren Tseng, Chan-Yu Chen, and Shih-Sheng Sun

pp 2711–2713

Publication Date (Web): January 26, 2011 (Communication)

DOI: 10.1021/ic101908p

New Three-Dimensional Metal−Organic Framework with Heterometallic [Fe−Ag] Building Units: Synthesis, Crystal Structure, and Functional Studies

Sanjit Nayak, Klaus Harms, and Stefanie Dehnen

pp 2714–2716

Publication Date (Web): March 1, 2011 (Communication)

DOI: 10.1021/ic1019636

 

Assembly of [Mn^II₂Mn^III₂] S = 9 Clusters via Azido Bridges: a New Single-Chain Magnet

Albert Escuer, Gina Vlahopoulou, and Franz A. Mautner

pp 2717–2719

Salen Complexes of Zirconium and Hafnium: Synthesis, Structural Characterization, Controlled Hydrolysis, and Solvent-Free Ring-Opening Polymerization of Cyclic Esters and Lactides

Tanmoy Kumar Saha, Venkatachalam Ramkumar, and Debashis Chakraborty

pp 2720–2722

Spontaneous Formation of Novel Luminescent Dinuclear Lanthanide Complexes That Emit in the Visible and Near-IR Regions

Claire Butler, Sandrine Goetz, Christopher M. Fitchett, Paul E. Kruger, and Thorfinnur Gunnlaugsson

pp 2723–2725

 

Exhaustive Chlorination of [B₁₂H₁₂]²⁻ without Chlorine Gas and the Use of [B₁₂Cl₁₂]²⁻ as a Supporting Anion in Catalytic Hydrodefluorination of Aliphatic C−F Bonds

Weixing Gu and Oleg V. Ozerov

pp 2726–2728

A Unique Three-Dimensional Coordination Cluster Based on a Silver Carbene Complex

Agnes Mrutu, Diane A. Dickie, Karen I. Goldberg, and Richard A. Kemp

pp 2729–2731

1,1′-Azobis(tetrazole): A Highly Energetic Nitrogen-Rich Compound with a N₁₀ Chain

Thomas M. Klaptke and Davin G. Piercey

pp 2732–2734

Stabilization of Magnetic Ordering Observed for the Bridging NCN Group

Jordan L. Arthur, Curtis E. Moore, Arnold L. Rheingold, and Joel S. Miller

pp 2735–2737

Examination of the Silver Colloid Binding Behavior of Disulfide-Tethered Bipyridine Ligands and Their fac-Tricarbonylrhenium(I) Complexes

Heather J. Montgomery, Diane Pelleteret, Steven E. J. Bell, and Nicholas C. Fletcher

pp 2738–2747

Bis(o-phenylenebis(acetylacetonato))dicopper(II): A Strained Copper(II) Dimer Exhibiting a Wide Range of Colors in the Solid State

Chandi Pariya, Frank R. Fronczek, and Andrew W. Maverick

pp 2748–2753

Structural, Electronic, and Acid/Base Properties of [Ru(bpy)₂(bpy(OH)₂)]²⁺ (bpy = 2,2′-Bipyridine, bpy(OH)₂ = 4,4′-Dihydroxy-2,2′-bipyridine)

Samantha Klein, William G. Dougherty, W. Scott Kassel, Timothy J. Dudley, and Jared J. Paul

pp 2754–2763

Complexation of Metal Ions, Including Alkali-Earth and Lanthanide(III) Ions, in Aqueous Solution by the Ligand 2,2′,6′,2′′-Terpyridyl

Joanna M. Hamilton, Michael J. Anhorn, Karen A. Oscarson, Joseph H. Reibenspies, and Robert D. Hancock

pp 2764–2770

Synthesis, Structure, and Reactivity of New Tetranuclear Ru-Hbpp-Based Water-Oxidation Catalysts

Laia Francs, Xavier Sala, Eduardo Escudero-Adn, Jordi Benet-Buchholz, Llus Escriche, and Antoni Llobet

pp 2771–2781

Light-Induced Excited Spin State Trapping and Charge Transfer in Trigonal Bipyramidal Cyanide-Bridged Complexes

Kristen E. Funck, Andrey V. Prosvirin, Corine Mathonire, Rodolphe Clrac, and Kim R. Dunbar

pp 2782–2789

Synthesis, Structure, and Spectroscopic Characterization of [H_8−nRh₂₂(CO)₃₅]ⁿ⁻ (n = 4, 5) and [H₂Rh₁₃(CO)₂₄{Cu(MeCN)}₂]⁻ Clusters: Assessment of CV and DPV As Techniques to Circumstantiate the Presence of Elusive Hydride Atoms

Davide Collini, Fabrizia Fabrizi De Biani, Dmitriy S. Dolzhnikov, Cristina Femoni, Maria C. Iapalucci, Giuliano Longoni, Cristina Tiozzo, Stefano Zacchini, and Piero Zanello

pp 2790–2798

Comprehensive Chemical Characterization of Complexes Involving Lead-Amino Acid Interactions

Cheryl D. L. Saunders, Lauren E. Longobardi, Neil Burford, Michael D. Lumsden, Ulrike Werner-Zwanziger, Banghao Chen, and Robert McDonald

pp 2799–2810

Hydrolysis of Uranyl(VI) in Acidic and Basic Aqueous Solutions Using a Noncomplexing Organic Base: A Multivariate Spectroscopic and Statistical Study

Fabienne Quils, Chinh Nguyen-Trung, Cdric Carteret, and Bernard Humbert

pp 2811–2823

Trifluorosulfane Ligand as an Analogue of the Nitrosyl Ligand: Highly Exothermic Fluorine Transfer Reactions from Sulfur to Metal in the Chemistry of SF₃ Metal Carbonyls of the First Row Transition Metals

Jianming Deng, Chaoyang Wang, Qian-shu Li, Yaoming Xie, R. Bruce King, and Henry F. Schaefer, III

pp 2824–2835

Hydrothermal Tm³⁺−Lu₂O₃ Nanorods with Highly Efficient 2 μm Emission

Ftima Esteban-Betegn, Carlos Zaldo, and Concepcin Cascales

pp 2836–2843

Three-Step Calcination Synthesis of High-Purity Li₈ZrO₆ with CO₂ Absorption Properties

Xian-Sheng Yin, Qin-Hui Zhang, and Jian-Guo Yu

pp 2844–2850

Unprecedented Lanthanide-Containing Coordination Polymers Constructed from Hexanuclear Molecular Building Blocks: {[Ln₆O(OH)₈](NO₃)₂(bdc)(Hbdc)₂·2NO₃·H₂bdc}_∞

Guillaume Calvez, Carole Daiguebonne, and Olivier Guillou

pp 2851–2858

Metal-Dependent and Redox-Selective Coordination Behaviors of Metalloligand [Mo^V(1,2-benzenedithiolato)₃]⁻ with Cu^I/Ag^I Ions

Takeshi Matsumoto, Ho-Chol Chang, Atsushi Kobayashi, Kohei Uosaki, and Masako Kato

pp 2859–2869

Synthesis and Characterization of Cerium and Yttrium Alkoxide Complexes Supported by Ferrocene-Based Chelating Ligands

Erin M. Broderick, Peter S. Thuy-Boun, Neng Guo, Carola S. Vogel, Jrg Sutter, Jeffrey T. Miller, Karsten Meyer, and Paula L. Diaconescu

pp 2870–2877

Investigation of the First-Order Phase Transition in the Co_1−xMg_xMoO₄ Solid Solution and Discussion of the Associated Thermochromic Behavior

L. C. Robertson, M. Gaudon, S. Jobic, P. Deniard, and A. Demourgues

pp 2878–2884

Characterization of a Tricationic Trigonal Bipyramidal Iron(IV) Cyanide Complex, with a Very High Reduction Potential, and Its Iron(II) and Iron(III) Congeners

Jason England, Erik R. Farquhar, Yisong Guo, Matthew A. Cranswick, Kallol Ray, Eckard Mnck, and Lawrence Que, Jr.

pp 2885–2896

The Thermal Stabilities of Luminescence and Microstructures of Eu²⁺-Doped KBaPO₄ and NaSrPO₄ with β-K₂SO₄ Type Structure

Suyin Zhang, Yosuke Nakai, Taiju Tsuboi, Yanlin Huang, and Hyo Jin Seo

pp 2897–2904

Direct Observation of Rare-Earth Ions in α-Sialon:Ce Phosphors

Fangfang Xu, Erwan Sourty, Wei Shi, Xinliang Mou, and Linlin Zhang

pp 2905–2910

Spin Structure of Surface-Supported Single-Molecule Magnets from Isomorphous Replacement and X-ray Magnetic Circular Dichroism

Matteo Mannini, Erik Tancini, Lorenzo Sorace, Philippe Sainctavit, Marie-Anne Arrio, Yu Qian, Edwige Otero, Daniele Chiappe, Ludovica Margheriti, Julio C. Cezar, Roberta Sessoli, and Andrea Cornia

pp 2911–2917

Syntheses, Electronic Structures, and EPR/UV−Vis−NIR Spectroelectrochemistry of Nickel(II), Copper(II), and Zinc(II) Complexes with a Tetradentate Ligand Based on S-Methylisothiosemicarbazide

Vladimir B. Arion, Peter Rapta, Joshua Telser, Sergiu S. Shova, Martin Breza, Karol Lupai, and Jozef Koiek

pp 2918–2931

Ultrafast Excited-State Dynamics of Rhenium(I) Photosensitizers [Re(Cl)(CO)₃(N,N)] and [Re(imidazole)(CO)₃(N,N)]⁺: Diimine Effects

Amal El Nahhas, Cristina Consani, Ana Mara Blanco-Rodrguez, Kyle M. Lancaster, Olivier Braem, Andrea Cannizzo, Michael Towrie, Ian P. Clark, Stanislav Zli, Majed Chergui, and Antonn Vlek, Jr.

pp 2932–2943

Catalytic Roles of the Metal Ion in the Substrate-Binding Site of Coenzyme B₁₂-Dependent Diol Dehydratase

Takashi Kamachi, Kazuki Doitomi, Masanori Takahata, Tetsuo Toraya, and Kazunari Yoshizawa

pp 2944–2952

Reversible Terbium Luminescent Polyelectrolyte Hydrogels for Detection of H₂PO₄⁻ and HSO₄⁻ in Water

Chaoliang Tan and Qianming Wang

pp 2953–2956

Family of Cadmium Acetate Coordination Networks With Structurally Diverse [Cd₄(OAc)₉(μ₃-OH)]²⁻ Secondary Building Units

Susan M. Vickers, Peter D. Frischmann, and Mark J. MacLachlan

pp 2957–2965

Crystal Structure and Morphology Evolution in the LaXO₃, X = Al, Ga, In Nano-Oxide Series. Consequences for the Synthesis of Luminescent Phosphors

Robert Pazik, Gulaim A. Seisenbaeva, Rafal J. Wiglusz, Leszek Kepinski, and Vadim G. Kessler

pp 2966–2974

Structure−Activity Relationship of Photocytotoxic Iron(III) Complexes of Modified Dipyridophenazine Ligands

Sounik Saha, Dibyendu Mallick, Ritankar Majumdar, Mithun Roy, Rajan R. Dighe, Eluvathingal D. Jemmis, and Akhil R. Chakravarty

pp 2975–2987

The Gas-Phase Equilibrium Structures of Si₈O₁₂(OSiMe₃)₈ and Si₈O₁₂(CHCH₂)₈

Derek A. Wann, Christopher N. Dickson, Paul D. Lickiss, Heather E. Robertson, and David W. H. Rankin

pp 2988–2994

Long-Range Spin Coupling: A Tetraphosphine-Bridged Palladium Dimer

Kuppuswamy Arumugam, Mohammed C. Shaw, Joel T. Mague, Eckhard Bill, Stephen Sproules, and James P. Donahue

pp 2995–3002

Ordering Double Perovskite Hydroxides by Kinetically Controlled Aqueous Hydrolysis

James R. Neilson, Joshua A. Kurzman, Ram Seshadri, and Daniel E. Morse

pp 3003–3009

Synthesis of Monomeric Fe(II) and Ru(II) Complexes of Tetradentate Phosphines

Barun Jana, Arkady Ellern, Oleg Pestovsky, Aaron Sadow, and Andreja Bakac

pp 3010–3016

Interaction of 1,3,2,4-Benzodithiadiazines and Their 1-Se Congeners with Ph₃P and Some Properties of the Iminophosphorane Products

Alexander Yu. Makarov, Vladimir V. Zhivonitko, Arkady G. Makarov, Samat B. Zikirin, Irina Yu. Bagryanskaya, Victor A. Bagryansky, Yuri V. Gatilov, Irina G. Irtegova, Makhmut M. Shakirov, and Andrey V. Zibarev

pp 3017–3027

Formation of Silicon Centered Spirocyclic Compounds: Reaction of N-Heterocyclic Stable Silylene with Benzoylpyridine, Diisopropyl Azodicarboxylate, and 1,2-Diphenylhydrazine

Ramachandran Azhakar, Sankaranarayana Pillai Sarish, Gaper Tavar, Herbert W. Roesky, Jakob Hey, Dietmar Stalke, and Debasis Koley

pp 3028–3036

Ba₃[Ge₂B₇O₁₆(OH)₂](OH)(H₂O) and Ba₃Ge₂B₆O₁₆: Novel Alkaline-Earth Borogermanates Based on Two Types of Polymeric Borate Units and GeO₄Tetrahedra

Jian-Han Zhang, Fang Kong, and Jiang-Gao Mao

pp 3037–3043

P₂²⁻ and P³⁻ Units in the [Rh₈P₉]^δ− Polyanion of La₄Rh₈P₉

Ulrike Pfannenschmidt, Dirk Johrendt, Frederik Behrends, Hellmut Eckert, Matthias Eul, and Rainer Pttgen

pp 3044–3051

Anion Dependent Redox Changes in Iron Bis-terdentate Nitroxide {NNO} Chelates

Ian A. Gass, Christopher J. Gartshore, David W. Lupton, Boujemaa Moubaraki, Ayman Nafady, Alan M. Bond, John F. Boas, John D. Cashion, Carsten Milsmann, Karl Wieghardt, and Keith S. Murray

pp 3052–3064

Synthesis of Cu_1.8S and CuS from Copper-Thiourea Containing Precursors; Anionic (Cl⁻, NO₃⁻, SO₄²⁻) Influence on the Product Stoichiometry

Prashant Kumar, Meenakshi Gusain, and R. Nagarajan

pp 3065–3070

A Study of the Kinetics of La³⁺-Promoted Methanolysis of S-Aryl Methylphosphonothioates: Possible Methodology for Decontamination of EA 2192, the Toxic Byproduct of VX Hydrolysis

Basab B. Dhar, David R. Edwards, and R. Stan Brown

pp 3071–3077

Isomeric Trimethylene and Ethylene Pendant-armed Cross-bridged Tetraazamacrocycles and in Vitro/in Vivo Comparisions of their Copper(II) Complexes

Antoinette Y. Odendaal, Ashley L. Fiamengo, Riccardo Ferdani, Thaddeus J. Wadas, Daniel C. Hill, Yijie Peng, Katie J. Heroux, James A. Golen, Arnold L. Rheingold, Carolyn J. Anderson, Gary R. Weisman, and Edward H. Wong

pp 3078–3086

Thermodynamic, Spectroscopic, and Computational Studies of Lanthanide Complexation with Diethylenetriaminepentaacetic Acid: Temperature Effect and Coordination Modes

Guoxin Tian, Leigh R. Martin, Zhiyong Zhang, and Linfeng Rao

pp 3087–3096

Additive Character of Electron Donation by Methyl Substituents within a Complete Series of Polymethylated [1-(η⁶-Me_nC₆H_6−n)-closo-1,2,3-FeC₂B₉H₁₁] Complexes. Linear Correlations of the NMR Parameters and Fe^II/III Redox Potentials with the Number of Arene Methyls

Bohumil tbr, Mario Bakardjiev, Josef Holub, Ale Rika, Zdeka Padlkov, and Petr tpnika

pp 3097–3102

Synthesis, Characterization, and Cytotoxicity of Platinum(IV) Carbamate Complexes

Justin J. Wilson and Stephen J. Lippard

pp 3103–3115

Publication Dat

Selective Anion Binding by a Cofacial Binuclear Zinc Complex of a Schiff-Base Pyrrole Macrocycle

Aline M. J. Devoille, Patricia Richardson, Nathan L. Bill, Jonathan L. Sessler, and Jason B. Love

pp 3116–3126

Designed Iron Carbonyls as Carbon Monoxide (CO) Releasing Molecules: Rapid CO Release and Delivery to Myoglobin in Aqueous Buffer, and Vasorelaxation of Mouse Aorta

Margarita A. Gonzalez, Nicole L. Fry, Richard Burt, Riddhi Davda, Adrian Hobbs, and Pradip K. Mascharak

pp 3127–3134

N−H Activation in N-Nitropropionamide: Coordination Chemistry of a Primary Nitroamide

D. Scott Bohle and Zhijie Chua

pp 3135–3140

QM and QM/MM Studies of Uranyl Fluorides in the Gas and Aqueous Phases and in the Hydrophobic Cavities of Tetrabrachion

Samuel O. Odoh, Sean M. Walker, Markus Meier, Jrg Stetefeld, and Georg Schreckenbach

pp 3141–3152

Effect of the Carboxylate Shift on the Reactivity of Zinc Complexes in the Gas Phase

Lucie Duchkov, Detlef Schrder, and Jana Roithov

pp 3153–3158

Synthesis, Electronic Structure, and Catalytic Activity of Reduced Bis(aldimino)pyridine Iron Compounds: Experimental Evidence for Ligand Participation

Sarah K. Russell, Carsten Milsmann, Emil Lobkovsky, Thomas Weyhermller, and Paul J. Chirik

pp 3159–3169