Inorganic chemistry v.50 n.9 2011

ISSN 0020-1669

Two Three-Dimensional 2p−3d−4f Heterometallic Frameworks Featuring a Ln₆Cu₂₄Na₁₂ Cluster as a Node

Gui-Lin Zhuang, Wen-Xian Chen, Hai-Xia Zhao, Xiang-Jian Kong, La-Sheng Long, Rong-Bin Huang, and Lan-Sun Zheng

pp 3843–3845

Publication Date (Web): April 1, 2011 (Communication)

DOI: 10.1021/ic200077r

C−N Bond-Forming Self-Condensation of Amide Promoted by MoCl₅ at Room Temperature

Sara Dolci, Fabio Marchetti, Guido Pampaloni, and Stefano Zacchini

pp 3846–3848

Publication Date (Web): March 31, 2011 (Communication)

DOI: 10.1021/ic2001199

Raising the Spin of Fe^III₇ Disklike Clusters: The Power of Molecular Spin Frustration

Shreya Mukherjee, Rashmi Bagai, Khalil A. Abboud, and George Christou

pp 3849–3851

Publication Date (Web): March 29, 2011 (Communication)

DOI: 10.1021/ic200256j

Dangling Thiyl Radical: Stabilized in [PPh₄]₂[(bdt)W^VI(O)(μ-S)₂Cu^I(SC₆H₄S^•)]

Moumita Bose, Golam Moula, Ameerunisha Begum, and Sabyasachi Sarkar

pp 3852–3854

Publication Date (Web): March 31, 2011 (Communication)

DOI: 10.1021/ic200258u

ARTICLES

Structural, Magnetic, and Gas Adsorption Study of a Series of Partially Fluorinated Metal−Organic Frameworks (HF-MOFs)

Pradip Pachfule, Raja Das, Pankaj Poddar, and Rahul Banerjee

pp 3855–3865

Publication Date (Web): March 25, 2011 (Article)

DOI: 10.1021/ic1017246

Synthesis, Characterization, and Reactivity Studies of Heterodinuclear Complexes Modeling Active Sites in Purple Acid Phospatases

Martin Jarenmark, Matti Haukka, Serhiy Demeshko, Felix Tuczek, Luca Zuppiroli, Franc Meyer, and Ebbe Nordlander

pp 3866–3887

Publication Date (Web): March 31, 2011 (Article)

DOI: 10.1021/ic1020324

Targeting Intermediates of [FeFe]-Hydrogenase by CO and CN Vibrational Signatures

Lian Yu, Claudio Greco, Maurizio Bruschi, Ulf Ryde, Luca De Gioia, and Markus Reiher

pp 3888–3900

Publication Date (Web): March 28, 2011 (Article)

DOI: 10.1021/ic102039z

High-Pressure Synthesis and Superconductivity of a New Binary Lanthanum Germanide LaGe₃ with Triangular Ge₃ Cluster Units

Hiroshi Fukuoka, Koichiro Suekuni, Takahiro Onimaru, and Kei Inumaru

pp 3901–3906

Publication Date (Web): March 29, 2011 (Article)

DOI: 10.1021/ic102077k

New Nickel Gallium Boride, B₁₄Ga₃Ni₂₇: Synthesis and Crystal Structure

Monique Tillard and Claude Belin

pp 3907–3912

Publication Date (Web): April 6, 2011 (Article)

DOI: 10.1021/ic102212n

Selective Americium(III) Complexation by Dithiophosphinates: A Density Functional Theoretical Validation for Covalent Interactions Responsible for Unusual Separation Behavior from Trivalent Lanthanides

Arunasis Bhattacharyya, Tapan Kumar Ghanty, Prasanta Kumar Mohapatra, and Vijay Kumar Manchanda

pp 3913–3921

Publication Date (Web): March 30, 2011 (Article)

DOI: 10.1021/ic102238c

New Phenoxido-Bridged Quasi-Tetrahedral and Rhomboidal [Cu₄] Compounds Bearing μ₄-Oxido or μ_1,1-Azido Ligands: Synthesis, Chemical Reactivity, and Magnetic Studies

Mrinal Sarkar, Rodolphe Cl rac, Corine Mathoni re, Nigel G. R. Hearns, Valerio Bertolasi, and Debashis Ray

pp 3922–3933

Publication Date (Web): April 4, 2011 (Article)

DOI: 10.1021/ic102226j

Selective Inactivation of Serine Proteases by Nonheme Iron Complexes

Jai Prakash and Jeremy J. Kodanko

pp 3934–3945

Publication Date (Web): April 6, 2011 (Article)

DOI: 10.1021/ic102320j

The Classic “Brown-Ring” Reaction in a New Medium: Kinetics, Mechanism, and Spectroscopy of the Reversible Binding of Nitric Oxide to Iron(II) in an Ionic Liquid

Svetlana Begel, Frank W. Heinemann, Grzegorz Stopa, Grazyna Stochel, and Rudi van Eldik

pp 3946–3958

Publication Date (Web): March 23, 2011 (Article)

DOI: 10.1021/ic1023357

Near-Infrared Absorbing and Emitting Ru^II−Pt^II Heterodimetallic Complexes of Dpdpz (Dpdpz = 2,3-Di(2-pyridyl)-5,6-diphenylpyrazine)

Si-Hai Wu, Stephen E. Burkhardt, Jiannian Yao, Yu-Wu Zhong, and H ctor D. Abru a

pp 3959–3969

Publication Date (Web): March 29, 2011 (Article)

DOI: 10.1021/ic1023696

Stack Pattern of the Countercation-Modulating Magnetic Property of Low-Dimensional [Pt(mnt)₂]⁻ Monoanion Spin Systems

Wen-Bo Pei, Jian-Sheng Wu, Zheng-Fang Tian, Xiao-Ming Ren, and You Song

pp 3970–3980

Publication Date (Web): April 4, 2011 (Article)

DOI: 10.1021/ic102406u

Orange and Yellow Crystals of Copper(I) Complexes Bearing 8-(Diphenylphosphino)quinoline: A Pair of Distortion Isomers of an Intrinsic Tetrahedral Complex

Takayoshi Suzuki, Hiroshi Yamaguchi, Akira Hashimoto, Koichi Nozaki, Mototsugu Doi, Naoya Inazumi, Noriaki Ikeda, Satoshi Kawata, Masaaki Kojima, and Hideo D. Takagi

pp 3981–3987

Publication Date (Web): March 29, 2011 (Article)

DOI: 10.1021/ic1024636

Fe-Site Substitution Effect on the Structural and Magnetic Properties in SrFeO₂

Liis Seinberg, Takafumi Yamamoto, C dric Tassel, Yoji Kobayashi, Naoaki Hayashi, Atsushi Kitada, Yuji Sumida, Takashi Watanabe, Masakazu Nishi, Kenji Ohoyama, Kazuyoshi Yoshimura, Mikio Takano, Werner Paulus, and Hiroshi Kageyama

pp 3988–3995

Publication Date (Web): March 31, 2011 (Article)

DOI: 10.1021/ic102467u

Mechanism of Al³⁺-Catalyzed Oxidations of Hydrocarbons: Dramatic Activation of H₂O₂ toward O−O Homolysis in Complex [Al(H₂O)₄(OOH)(H₂O₂)]²⁺ Explains the Formation of HO^• Radicals

Maxim L. Kuznetsov, Yuriy N. Kozlov, Dalmo Mandelli, Armando J. L. Pombeiro, and Georgiy B. Shul’pin

pp 3996–4005

Publication Date (Web): April 1, 2011 (Article)

DOI: 10.1021/ic102476x

Two Novel Cyanide-Bridged Bimetallic Magnetic Chains Derived from Manganese(III) Schiff Bases and Hexacyanochromate(III) Building Blocks

Chun Yang, Qing-Lun Wang, Jing Qi, Yue Ma, Shi-Ping Yan, Guang-Ming Yang, Peng Cheng, and Dai-Zheng Liao

pp 4006–4015

Publication Date (Web): March 28, 2011 (Article)

DOI: 10.1021/ic102495t

Mononuclear Fe^II Single-Molecule Magnets: A Theoretical Approach

Eduard Cremades and Eliseo Ruiz

pp 4016–4020

Publication Date (Web): April 1, 2011 (Article)

DOI: 10.1021/ic102514a

Heteroatomic Molecular Clusters Derived from Group 15 Zintl Ion Cages: Synthesis and Isolation of [M₂(HP₇)₂]²⁻ (M = Ag, Au), Two Novel Cluster Anions Exhibiting Metallophilic Interactions

Caroline M. Knapp, Charlotte S. Jackson, Joseph S. Large, Amber L. Thompson, and Jose M. Goicoechea

pp 4021–4028

Publication Date (Web): March 22, 2011 (Article)

DOI: 10.1021/ic102516g

Cyclam-methylbenzimidazole: a Selective OFF-ON Fluorescent Sensor for Zinc

Abir El Majzoub, Cyril Cadiou, Isabelle D champs-Olivier, Bernard Tinant, and Fran oise Chuburu

pp 4029–4038

Publication Date (Web): April 5, 2011 (Article)

DOI: 10.1021/ic102521g

Chiral Semiconductor Phases: The Optically Pure D₃[M^III(S,S-EDDS)]₂ (D = TTF, TSF) Family

Nikola Paul Chmel, Guy J. Clarkson, Alessandro Troisi, Scott S. Turner, and Peter Scott

pp 4039–4046

Publication Date (Web): April 4, 2011 (Article)

DOI: 10.1021/ic102522k

Halide Coordination of Perhalocyclohexasilane Si₆X₁₂ (X = Cl or Br)

Xuliang Dai, Seok-Bong Choi, Christopher W. Braun, Pooja Vaidya, Svetlana Kilina, Angel Ugrinov, Douglas L. Schulz, and Philip Boudjouk

pp 4047–4053

Publication Date (Web): April 4, 2011 (Article)

DOI: 10.1021/ic102535n

Syntheses and Surprising Regioselectivity of 5- and 6-Substituted Decaboranyl Ethers via the Nucleophilic Attack of Alcohols on 6- and 5-Halodecaboranes

William C. Ewing, Patrick J. Carroll, and Larry G. Sneddon

pp 4054–4064

Publication Date (Web): March 31, 2011 (Article)

DOI: 10.1021/ic102544v

Facile Synthesis of ZnS−CuInS₂-Alloyed Nanocrystals for a Color-Tunable Fluorchrome and Photocatalyst

Wenjin Zhang and Xinhua Zhong

pp 4065–4072

Publication Date (Web): April 1, 2011 (Article)

DOI: 10.1021/ic102559e

Incorporating Peptides in the Outer-Coordination Sphere of Bioinspired Electrocatalysts for Hydrogen Production

Avijita Jain, Sheri Lense, John C. Linehan, Simone Raugei, Herman Cho, Daniel L. DuBois, and Wendy J. Shaw

pp 4073–4085

Publication Date (Web): April 1, 2011 (Article)

DOI: 10.1021/ic1025872

Structures and Redox Characteristics of Electron-Deficient Vanadyl Phthalocyanines

Łukasz Łapok, Martin Lener, Olga Tsaryova, Stefanie Nagel, Christopher Keil, Robert Gerdes, Derck Schlettwein, and Sergiu M. Gorun

pp 4086–4091

Publication Date (Web): April 5, 2011 (Article)

DOI: 10.1021/ic2000365

Coordination and Reductive Chemistry of Tetraphenylborate Complexes of Trivalent Rare Earth Metallocene Cations, [(C₅Me₅)₂Ln][(μ-Ph)₂BPh₂]

Matthew R. MacDonald, Joseph W. Ziller, and William J. Evans

pp 4092–4106

Publication Date (Web): March 25, 2011 (Article)

DOI: 10.1021/ic2000409

Family of Cofacial Bimetallic Complexes of a Hexaanionic Carboxamide Cryptand

Glen E. Alliger, Peter M ller, Loi H. Do, Christopher C. Cummins, and Daniel G. Nocera

pp 4107–4115

Publication Date (Web): March 29, 2011 (Article)

DOI: 10.1021/ic200143b

Self-Assembled β-NaGdF₄ Microcrystals: Hydrothermal Synthesis, Morphology Evolution, and Luminescence Properties

Fei He, Piaoping Yang, Dong Wang, Na Niu, Shili Gai, and Xingbo Li

pp 4116–4124

Publication Date (Web): April 6, 2011 (Article)

DOI: 10.1021/ic200155q

Lanthanide dota-like Complexes Containing a Picolinate Pendant: Structural Entry for the Design of Ln^III-Based Luminescent Probes

Mart n Regueiro-Figueroa, Bachir Bensenane, Erika Ruscs k, David Esteban-G mez, Lo c J. Charbonni re, Gyula Tircs , Imre T th, Andr s de Blas, Teresa Rodr guez-Blas, and Carlos Platas-Iglesias

pp 4125–4141

Publication Date (Web): April 1, 2011 (Article)

DOI: 10.1021/ic2001915

On the Magnetic Insulating States, Spin Frustration, and Dominant Spin Exchange of the Ordered Double-Perovskites Sr₂CuOsO₆ and Sr₂NiOsO₆: Density Functional Analysis

Chuan Tian, Arief C. Wibowo, Hans-Conrad zur Loye, and Myung-Hwan Whangbo

pp 4142–4148

Publication Date (Web): March 28, 2011 (Article)

DOI: 10.1021/ic200167j

m-Carborane-Based Chiral NBN Pincer-Metal Complexes: Synthesis, Structure, and Application in Asymmetric Catalysis

Mohamed E. El-Zaria, Hidekazu Arii, and Hiroyuki Nakamura

pp 4149–4161

Publication Date (Web): March 25, 2011 (Article)

DOI: 10.1021/ic2002095

Zn(II)−Cyclam Based Chromogenic Sensors for Recognition of ATP in Aqueous Solution Under Physiological Conditions and Their Application as Viable Staining Agents for Microorganism

Prasenjit Mahato, Amrita Ghosh, Sanjiv K. Mishra, Anupama Shrivastav, Sandhya Mishra, and Amitava Das

pp 4162–4170

Publication Date (Web): March 30, 2011 (Article)

DOI: 10.1021/ic200223g

Syntheses, Crystal Structures, Transport Properties and First-Principles Electronic Structure Study of the (tTTF)₂X (X = Br, I) Low-Dimensional Antiferromagnets

Marc Fourmigu , Eric W. Reinheimer, Ali Assaf, Olivier Jeannin, and Ali Saad , Pascale Auban-Senzier , Pere Alemany , Antonio Rodr guez-Fortea , Enric Canadell

pp 4171–4181

Publication Date (Web): March 29, 2011 (Article)

DOI: 10.1021/ic2002964

On the High Magnetic-Ordering Temperature of the 5d Magnetic Oxide Ca₃LiOsO₆ Crystallizing in a Trigonal Crystal Structure: Density Functional Analysis

Erjun Kan, Fang Wu, Changhoon Lee, Jinhee Kang, and Myung-Hwan Whangbo

pp 4182–4186

Publication Date (Web): March 25, 2011 (Article)

DOI: 10.1021/ic200305a

Cobalt-Mediated Selective B−H Activation and Formation of a Co−B Bond in the Reaction of the 16-Electron CpCo Half-Sandwich Complex Containing an o-Carborane-1,2-dithiolate Ligand with Ethyl Diazoacetate

Guifeng Liu, Jiurong Hu, Jialin Wen, Huimin Dai, Yizhi Li, and Hong Yan

pp 4187–4194

Publication Date (Web): March 28, 2011 (Article)

DOI: 10.1021/ic200333q

Pt(II) and Pt(IV) Amido, Aryloxide, and Hydrocarbyl Complexes: Synthesis, Characterization, and Reaction with Dihydrogen and Substrates that Possess C−H Bonds

Joanna R. Webb, Colleen Munro-Leighton, Aaron W. Pierpont, Joshua T. Gurkin, T. Brent Gunnoe, Thomas R. Cundari, Michal Sabat, Jeffrey L. Petersen, and Paul D. Boyle

pp 4195–4211

Publication Date (Web): March 28, 2011 (Article)

DOI: 10.1021/ic200153n

Unprecedented 1,3-Diaza[3]ferrocenophane Scaffold as Molecular Probe for Anions

Antonia Sola, Ra l A. Orenes, Mar a  ngeles Garc a, Rosa M. Claramunt, Ibon Alkorta, Jos  Elguero, Alberto T rraga, and Pedro Molina

pp 4212–4220

Publication Date (Web): February 14, 2011 (Article)

DOI: 10.1021/ic102314r

ADDITIONS AND CORRECTIONS

Correction to Density Functional Theory Calculations on M ssbauer Parameters of Nonheme Iron Nitrosyls

Kathrin H. Hopmann, Abhik Ghosh, and Louis Noodleman

p 4221

Publication Date (Web): March 31, 2011 (Addition/Correction)

DOI: 10.1021/ic200575z