Journal of the American Chemical Society v.133 n.28 2011

ISSN 0002-7863

COMMUNICATIONS

Size-Dependent Hydrogen Storage Properties of Mg Nanocrystals Prepared from Solution

Nick S. Norberg, Timothy S. Arthur, Sarah J. Fredrick, and Amy L. Prieto

pp 10679–10681

Publication Date (Web): June 14, 2011 (Communication)

DOI: 10.1021/ja201791y

Bent Alkanes in a New Thiourea-Containing Capsule

Ali Asadi, Dariush Ajami, and Julius Rebek, Jr.

pp 10682–10684

Publication Date (Web): June 21, 2011 (Communication)

DOI: 10.1021/ja203602u

Observation of Inhomogeneity in the Lipid Composition of Individual Nanoscale Liposomes

Jannik Larsen, Nikos S. Hatzakis, and Dimitrios Stamou

pp 10685–10687

Publication Date (Web): June 20, 2011 (Communication)

DOI: 10.1021/ja203984j

Spontaneous Self-Organization Enables Dielectrophoresis of Small Nanoparticles and Formation of Photoconductive Microbridges

Seung-Ho Jung, Chen Chen, Sang-Ho Cha, Bongjun Yeom, Joong Hwan Bahng, Sudhanshu Srivastava, Jian Zhu, Ming Yang, Shaoqin Liu, and Nicholas A. Kotov

pp 10688–10691

Publication Date (Web): June 9, 2011 (Communication)

DOI: 10.1021/ja200422s

CO-Induced Embedding of Pt Adatoms in a Partially Reduced FeO_x Film on Pt(111)

Lindsay R. Merte, Jan Knudsen, Falk M. Eichhorn, Soeren Porsgaard, Helene Zeuthen, Lars C. Grabow, Erik Lægsgaard, Hendrik Bluhm, Miquel Salmeron, Manos Mavrikakis, and Flemming Besenbacher

pp 10692–10695

Publication Date (Web): June 27, 2011 (Communication)

DOI: 10.1021/ja2015923

Chiral Ruthenabicyclic Complexes: Precatalysts for Rapid, Enantioselective, and Wide-Scope Hydrogenation of Ketones

Kazuhiko Matsumura, Noriyoshi Arai, Kiyoto Hori, Takao Saito, Noboru Sayo, and Takeshi Ohkuma

pp 10696–10699

Publication Date (Web): June 16, 2011 (Communication)

DOI: 10.1021/ja202296w

Room Temperature Dehydrogenation of Ethane to Ethylene

Vincent N. Cavaliere, Marco G. Crestani, Balazs Pinter, Maren Pink, Chun-Hsing Chen, Mu-Hyun Baik, and Daniel J. Mindiola

pp 10700–10703

Publication Date (Web): June 16, 2011 (Communication)

DOI: 10.1021/ja202316m

Effect of the F610A Mutation on Substrate Extrusion in the AcrB Transporter: Explanation and Rationale by Molecular Dynamics Simulations

Attilio V. Vargiu, Francesca Collu, Robert Schulz, Klaas M. Pos, Martin Zacharias, Ulrich Kleinekath fer, and Paolo Ruggerone

pp 10704–10707

Publication Date (Web): June 27, 2011 (Communication)
DOI: 10.1021/ja202666x

Traceless and Site-Specific Ubiquitination of Recombinant Proteins

Satpal Virdee, Prashant B. Kapadnis, Thomas Elliott, Kathrin Lang, Julia Madrzak, Duy P. Nguyen, Lutz Riechmann, and Jason W. Chin

pp 10708–10711

Publication Date (Web): June 28, 2011 (Communication)

DOI: 10.1021/ja202799r

Breaking Symmetry toward Nonspherical Janus Particles Based on Polyhedral Oligomeric Silsesquioxanes: Molecular Design, “Click” Synthesis, and Hierarchical Structure

Yiwen Li, Wen-Bin Zhang, I-Fan Hsieh, Guoliang Zhang, Yan Cao, Xiaopeng Li, Chrys Wesdemiotis, Bernard Lotz, Huiming Xiong, and Stephen Z. D. Cheng

pp 10712–10715

Publication Date (Web): June 16, 2011 (Communication)

DOI: 10.1021/ja202906m

Direct Arylation of Polycyclic Aromatic Hydrocarbons through Palladium Catalysis

Kenji Mochida, Katsuaki Kawasumi, Yasutomo Segawa, and Kenichiro Itami

pp 10716–10719

Publication Date (Web): June 23, 2011 (Communication)

DOI: 10.1021/ja202975w

Tetravalent Metal Complexes as a New Family of Catalysts for Copolymerization of Epoxides with Carbon Dioxide

Koji Nakano, Kazuki Kobayashi, and Kyoko Nozaki

pp 10720–10723

Publication Date (Web): June 21, 2011 (Communication)

DOI: 10.1021/ja203382q

Ring-Opening Copolymerization of Maleic Anhydride with Epoxides: A Chain-Growth Approach to Unsaturated Polyesters

Angela M. DiCiccio and Geoffrey W. Coates

pp 10724–10727

Publication Date (Web): June 24, 2011 (Communication)

DOI: 10.1021/ja203520p

Bulky, Optically Active P-Stereogenic Phosphine–Boranes from Pure H-Menthylphosphinates

David Gatineau, Laurent Giordano, and G rard Buono

pp 10728–10731

Publication Date (Web): June 16, 2011 (Communication)

DOI: 10.1021/ja2034816

4D Scanning Transmission Ultrafast Electron Microscopy: Single-Particle Imaging and Spectroscopy

Volkan Ortalan and Ahmed H. Zewail

pp 10732–10735

Publication Date (Web): May 26, 2011 (Communication)

DOI: 10.1021/ja203821y

Segregated Donor–Acceptor Columns in Liquid Crystals That Exhibit Highly Efficient Ambipolar Charge Transport

Hironobu Hayashi, Wataru Nihashi, Tomokazu Umeyama, Yoshihiro Matano, Shu Seki, Yo Shimizu, and Hiroshi Imahori

pp 10736–10739

Publication Date (Web): June 23, 2011 (Communication)

DOI: 10.1021/ja203822q

Diverse Fragment Clustering and Water Exclusion Identify Protein Hot Spots

John L. Kulp, III, John L. Kulp, Jr., David L. Pompliano, and Frank Guarnieri

pp 10740–10743

Publication Date (Web): June 17, 2011 (Communication)

DOI: 10.1021/ja203929x

Visualizing Zeptomole (Electro)Catalysis at Single Nanoparticles within an Ensemble

Stanley C.S. Lai, Petr V. Dudin, Julie V. Macpherson, and Patrick R. Unwin

pp 10744–10747

Publication Date (Web): June 14, 2011 (Communication)

DOI: 10.1021/ja203955b

Transpeptidase-Mediated Incorporation of d-Amino Acids into Bacterial Peptidoglycan

Tania J. Lupoli, Hirokazu Tsukamoto, Emma H. Doud, Tsung-Shing Andrew Wang, Suzanne Walker, and Daniel Kahne

pp 10748–10751

Publication Date (Web): June 17, 2011 (Communication)

DOI: 10.1021/ja2040656

Post-Self-Assembly Covalent Chemistry of Discrete Multicomponent Metallosupramolecular Hexagonal Prisms

Ming Wang, Wen-Jie Lan, Yao-Rong Zheng, Timothy R. Cook, Henry S. White, and Peter J. Stang

pp 10752–10755

Publication Date (Web): June 14, 2011 (Communication)

DOI: 10.1021/ja204155r

Iron-Catalyzed Carbonylation-Peroxidation of Alkenes with Aldehydes and Hydroperoxides

Weiping Liu, Yuanming Li, Kaisheng Liu, and Zhiping Li

pp 10756–10759

Publication Date (Web): June 20, 2011 (Communication)

DOI: 10.1021/ja204226n

Plasmonic Vesicles of Amphiphilic Gold Nanocrystals: Self-Assembly and External-Stimuli-Triggered Destruction

Jibin Song, Lin Cheng, Aiping Liu, Jun Yin, Min Kuang, and Hongwei Duan

pp 10760–10763

Publication Date (Web): June 23, 2011 (Communication)

DOI: 10.1021/ja204387w

Rational Design of a Ternary Supramolecular System: Self-Assembly of Pentanuclear Lanthanide Helicates

Badr El Aroussi, Soumaila Zebret, C line Besnard, Philippe Perrottet, and Josef Hamacek

pp 10764–10767

Publication Date (Web): June 20, 2011 (Communication)

DOI: 10.1021/ja204474v

Concise Total Synthesis and Stereochemical Revision of all (−)-Trigonoliimines

Sunkyu Han and Mohammad Movassaghi

pp 10768–10771

Publication Date (Web): June 13, 2011 (Communication)

DOI: 10.1021/ja204597k

Crystallographic X-ray Analyses of Yb@C_2v(3)-C₈₀ Reveal a Feasible Rule That Governs the Location of a Rare Earth Metal inside a Medium-Sized Fullerene

Xing Lu, Yongfu Lian, Christine M. Beavers, Naomi Mizorogi, Zdenek Slanina, Shigeru Nagase, and Takeshi Akasaka

pp 10772–10775

Publication Date (Web): June 17, 2011 (Communication)

DOI: 10.1021/ja204653z

Metallohosts with a Heart of Carbon

Edwin C. Constable, Guoqi Zhang, Daniel H ussinger, Catherine E. Housecroft, and Jennifer A. Zampese

pp 10776–10779

Publication Date (Web): June 22, 2011 (Communication)

DOI: 10.1021/ja204888w

Tissue Morphing Control on Dynamic Gradient Surfaces

Wei Luo and Muhammad N. Yousaf

pp 10780–10783

Publication Date (Web): June 27, 2011 (Communication)

DOI: 10.1021/ja204893w

An Advance in Proline Ligation

Shiying Shang, Zhongping Tan, Suwei Dong, and Samuel J. Danishefsky

pp 10784–10786

Publication Date (Web): June 23, 2011 (Communication)

DOI: 10.1021/ja204277b

Direct Michael Addition of Alkenes via a Cobalt-Dinitrosyl Mediated Vinylic C–H Functionalization Reaction

Chen Zhao, F. Dean Toste, and Robert G. Bergman

pp 10787–10789

Publication Date (Web): June 23, 2011 (Communication)

DOI: 10.1021/ja204564z

ARTICLES

Diastereodivergent Behavior of Alkyl versus Cyano Allenylcuprates toward Aldehydes: A Key Role for Lithium

Emmanuel Vrancken, H l ne G rard, David Linder, Souad Ouizem, Nacira Alouane, Eve Roubineau, Kamel Bentayeb, J r me Marrot, and Pierre Mangeney

pp 10790–10802

Publication Date (Web): June 9, 2011 (Article)

DOI: 10.1021/ja200702a

Products and Mechanism of Acene Dimerization. A Computational Study

Sanjio S. Zade, Natalia Zamoshchik, A. Ravikumar Reddy, Galit Fridman-Marueli, Dennis Sheberla, and Michael Bendikov

pp 10803–10816

Publication Date (Web): May 21, 2011 (Article)

DOI: 10.1021/ja106594v

Free Energy Calculations on the Two Drug Binding Sites in the M2 Proton Channel

Ruo-Xu Gu, Limin Angela Liu, Dong-Qing Wei, Jian-Guo Du, Lei Liu, and Hong Liu

pp 10817–10825

Publication Date (Web): June 28, 2011 (Article)

DOI: 10.1021/ja1114198

Thermally Driven Ionic Aggregation in Poly(ethylene oxide)-Based Sulfonate Ionomers

Wenqin Wang, Gregory J. Tudryn, Ralph H. Colby, and Karen I. Winey

pp 10826–10831

Publication Date (Web): June 24, 2011 (Article)

DOI: 10.1021/ja201405v

Formation of a Mesoscopic Skin Barrier in Mesoglobules of Thermoresponsive Polymers

Matthias J. N. Junk, Wen Li, A. Dieter Schl ter, Gerhard Wegner, Hans W. Spiess, Afang Zhang, and Dariush Hinderberger

pp 10832–10838

Publication Date (Web): June 10, 2011 (Article)

DOI: 10.1021/ja201217d

Unexpected Tricovalent Binding Mode of Boronic Acids within the Active Site of a Penicillin-Binding Protein

Astrid Zervosen, Raphael Herman, Fr d ric Kerff, Alexandre Herman, Andr  Bouillez, Fabio Prati, R. F. Pratt, Jean-Marie Fr re, Bernard Joris, Andr  Luxen, Paulette Charlier, and Eric Sauvage

pp 10839–10848

Publication Date (Web): May 16, 2011 (Article)

DOI: 10.1021/ja200696y

Probing Multivalent Interactions in a Synthetic Host–Guest Complex by Dynamic Force Spectroscopy

Alberto Gomez-Casado, Henk H. Dam, M. Deniz Yilmaz, Daniel Florea, Pascal Jonkheijm, and Jurriaan Huskens

pp 10849–10857

Publication Date (Web): May 26, 2011 (Article)

DOI: 10.1021/ja2016125

Graphene Actuators: Quantum-Mechanical and Electrostatic Double-Layer Effects

Geoffrey W. Rogers and Jefferson Z. Liu

pp 10858–10863

Publication Date (Web): June 14, 2011 (Article)

DOI: 10.1021/ja201887r

Mechanisms of the Thermal Cyclotrimerizations of Fluoro- and Chloroacetylenes: Density Functional Theory Investigation and Intermediate Trapping Experiments

Zhong-Ke Yao and Zhi-Xiang Yu

pp 10864–10877

Publication Date (Web): June 23, 2011 (Article)

DOI: 10.1021/ja2021476

Highly Efficient Visible-Light-Driven Photocatalytic Hydrogen Production of CdS-Cluster-Decorated Graphene Nanosheets

Qin Li, Beidou Guo, Jiaguo Yu, Jingrun Ran, Baohong Zhang, Huijuan Yan, and Jian Ru Gong

pp 10878–10884

Publication Date (Web): June 3, 2011 (Article)

DOI: 10.1021/ja2025454

Reversible and Selective O₂ Chemisorption in a Porous Metal–Organic Host Material

Peter D. Southon, David J. Price, Pia K. Nielsen, Christine J. McKenzie, and Cameron J. Kepert

pp 10885–10891

Publication Date (Web): June 3, 2011 (Article)

DOI: 10.1021/ja202228v

Building Custom Polysaccharides in Vitro with an Efficient, Broad-Specificity Xyloglucan Glycosynthase and a Fucosyltransferase

Oliver Spadiut, Farid M. Ibatullin, Jonelle Peart, Fredrika Gullfot, Carlos Martinez-Fleites, Marcus Ruda, Chunlin Xu, Gustav Sundqvist, Gideon J. Davies, and Harry Brumer

pp 10892–10900

Publication Date (Web): May 27, 2011 (Article)

DOI: 10.1021/ja202788q

Unprecedented Robust Antiferromagnetism in Fluorinated Hexagonal Perovskites

Mihai Sturza, Houria Kabbour, Sylvie Daviero-Minaud, Dmitry Filimonov, Konstantin Pokholok, Nicolas Tiercelin, Florence Porcher, Laurent Aldon, and Olivier Mentr

pp 10901–10909

Publication Date (Web): June 7, 2011 (Article)

DOI: 10.1021/ja2028603

Peptoid Atropisomers
Bishwajit Paul, Glenn L. Butterfoss, Mikki G. Boswell, P. Douglas Renfrew, Fanny G. Yeung, Neel H. Shah, Christian Wolf, Richard Bonneau, and Kent Kirshenbaum

pp 10910–10919

Publication Date (Web): June 2, 2011 (Article)

DOI: 10.1021/ja2028684

Thermoelectrics from Abundant Chemical Elements: High-Performance Nanostructured PbSe–PbS

John Androulakis, Iliya Todorov, Jiaqing He, Duck-Young Chung, Vinayak Dravid, and Mercouri Kanatzidis

pp 10920–10927

Publication Date (Web): June 8, 2011 (Article)

DOI: 10.1021/ja203022c

Selective Catalytic Reduction at Quasi-Perfect Pt(100) Domains: A Universal Low-Temperature Pathway from Nitrite to N₂

Matteo Duca, Marta C. Figueiredo, Victor Climent, Paramaconi Rodriguez, Juan M. Feliu, and Marc T. M. Koper

pp 10928–10939

Publication Date (Web): May 31, 2011 (Article)

DOI: 10.1021/ja203234v

Self-Assembly of Focal Point Oligo-catechol Ethylene Glycol Dendrons on Titanium Oxide Surfaces: Adsorption Kinetics, Surface Characterization, and Nonfouling Properties

Torben Gillich, Edmondo M. Benetti, Ekaterina Rakhmatullina, Rupert Konradi, Wen Li, Afang Zhang, A. Dieter Schl ter, and Marcus Textor

pp 10940–10950

Publication Date (Web): June 2, 2011 (Article)

DOI: 10.1021/ja202760x

On the Mechanism of Dimethylarginine Dimethylaminohydrolase Inactivation by 4-Halopyridines

Corey M. Johnson, Arthur F. Monzingo, Zhihong Ke, Dae-Wi Yoon, Thomas W. Linsky, Hua Guo, Jon D. Robertus, and Walter Fast

pp 10951–10959

Publication Date (Web): June 1, 2011 (Article)

DOI: 10.1021/ja2033684

A Unique Paradigm for a Turn-ON Near-Infrared Cyanine-Based Probe: Noninvasive Intravital Optical Imaging of Hydrogen Peroxide

Naama Karton-Lifshin, Ehud Segal, Liora Omer, Moshe Portnoy, Ronit Satchi-Fainaro, and Doron Shabat

pp 10960–10965

Publication Date (Web): June 2, 2011 (Article)

DOI: 10.1021/ja203145v

Thermoresponsive Dynamers: Thermally Induced, Reversible Chain Elongation of Amphiphilic Poly(acylhydrazones)

J. Frantz Folmer-Andersen and Jean-Marie Lehn

pp 10966–10973

Publication Date (Web): June 3, 2011 (Article)

DOI: 10.1021/ja2035909

Nonnative Interactions in the FF Domain Folding Pathway from an Atomic Resolution Structure of a Sparsely Populated Intermediate: An NMR Relaxation Dispersion Study

Dmitry M. Korzhnev, Robert M. Vernon, Tomasz L. Religa, Alexandar L. Hansen, David Baker, Alan R. Fersht, and Lewis E. Kay

pp 10974–10982

Publication Date (Web): June 6, 2011 (Article)

DOI: 10.1021/ja203686t

Disruption of Supported Lipid Bilayers by Semihydrophobic Nanoparticles

Benxin Jing and Yingxi Zhu

pp 10983–10989

Publication Date (Web): June 1, 2011 (Article)

DOI: 10.1021/ja2040305

Nongenetic Reprogramming of a Fungal Highly Reducing Polyketide Synthase
Ahmed A. Yakasai, Jack Davison, Zahida Wasil, Laura M. Halo, Craig P. Butts, Colin M. Lazarus, Andrew M. Bailey, Thomas J. Simpson, and Russell J. Cox

pp 10990–10998

Publication Date (Web): June 15, 2011 (Article)

DOI: 10.1021/ja204200x

Rational Catalysis Design on the Basis of Mechanistic Understanding: Highly Efficient Pd-Catalyzed Cyanation of Aryl Bromides with NaCN in Recyclable Solvents

Alexander V. Ushkov and Vladimir V. Grushin

pp 10999–11005

Publication Date (Web): June 23, 2011 (Article)

DOI: 10.1021/ja2042035

ADDITIONS AND CORRECTIONS

Protonolysis of a Ruthenium–Carbene Bond and Applications in Olefin Metathesis

Benjamin K. Keitz, Jean Bouffard, Guy Bertrand, and Robert H. Grubbs

p 11006

Publication Date (Web): June 23, 2011 (Addition/Correction)

DOI: 10.1021/ja204984r